Here is the full list of all 69 Borderlands 2 VR achievements.
Completed level 1 of all non-level-specific challenges with a single character
Completed all side missions
Discovered all named locations
Collected 10 pictures of Moxxi in Campaign of Carnage
I can't even capture it on my camera
Defeated Terramorphous the Invincible
Discovered all named locations in Hammerlock's Hunt
Completed all Hammerlock's Hunt side missions
Won the most challenging round in Murderlin's Temple
Vanquished the Ancient Dragons of Destruction
Discovered all named locations in Oasis and the surrounding Pirate's Booty zones
Completed all Campaign of Carnage side missions
Completed all Pirate's Booty side missions
Fed thy noble queen 3 times during one visit to her quarters
Discovered all named locations in Eridium Blight, Arid Nexus, and Sawtooth Cauldron
Showed thine worst enemy, the abomination known as "The Darkness," who is the nerdiest of them all
Wielded the Mysterious Amulet
Discovered all named locations in Three Horns, Tundra Express, and Frostburn Canyon
Discovered all named locations in The Highlands, Thousand Cuts, and Wildlife Exploitation Preserve
Completed the mission "Long Way To The Top"
Completed the mission "The Fall of Nakayama"
Remained in Zero's Deception mode for ten seconds straight
Completed thy quest by rescuing yonder queen
Gunzerked continuously for 90 seconds
Demonstrated your skill, or lack thereof, at rolling the magical treasure orb of many sides
Completed the mission "X Marks the Spot"
Killed Donkey Mong
Opened the chest at the bus stop in Fyrestone
Reached level 50
Phaselocked 100 enemies
Completed Round 5 of any Circle of Slaughter
Gave Claptrap a high five
Got an item from Michael Mamaril
Had Purple-rated gear or better equipped in every slot
Killed a Chubby
Killed 100 enemies with the Sabre turret
Unsheathed 5 swords from Immortal Skeletaurs without leaving the area
Introduced thyself to the White Knight
Slew Mister Boney Pants Guy
Defeated Jack
Completed the mission "Data Mining"
Killed a flying enemy with a thrown Tediore weapon
Completed the mission "Toil And Trouble"
Completed the mission "Where Angels Fear To Tread"
Discovered all named locations in Sanctuary, Opportunity, and Lynchwood
Tipped Moxxi $10,000
Killed 5 enemies during a single use of BAMF Time
Reached level 25
Completed the mission "The Man Who Would Be Jack"
Completed the mission "The Once and Future Slab"
Completed the mission "Shoot This Guy in the Face"
Completed the mission "Wildlife Preservation"
Completed the mission "Bright Lights, Flying City"
Completed the mission "Rising Action"
Completed the mission "A Train To Catch"
Killed a Constructor without it ever building another bot
Completed the mission "A Dam Fine Rescue"
Completed 20 side missions
Unlocked 10 customization items
Purchased 5 items from the black market
Redeemed 25 tokens
Completed the mission "Hunting The Firehawk"
Allowed a Goliath to level up four times before killing him
Reached level 10
Completed the mission "Plan B"
Completed the mission "The Road To Sanctuary"
Completed the mission "Best Minion Ever"
Reached level 5
Completed the mission "My First Gun"