Here is the full list of all 69 Borderlands 2 VR achievements.
Remained in Zero's Deception mode for ten seconds straight
Killed 100 enemies with the Sabre turret
Phaselocked 100 enemies
Completed all side missions
Defeated Terramorphous the Invincible
Completed all Campaign of Carnage side missions
Won the most challenging round in Murderlin's Temple
Vanquished the Ancient Dragons of Destruction
Reached level 50
Wielded the Mysterious Amulet
Fed thy noble queen 3 times during one visit to her quarters
Completed thy quest by rescuing yonder queen
Showed thine worst enemy, the abomination known as "The Darkness," who is the nerdiest of them all
Demonstrated your skill, or lack thereof, at rolling the magical treasure orb of many sides
Unsheathed 5 swords from Immortal Skeletaurs without leaving the area
Introduced thyself to the White Knight
Slew Mister Boney Pants Guy
Completed all Hammerlock's Hunt side missions
Discovered all named locations in Hammerlock's Hunt
Completed the mission "The Fall of Nakayama"
Collected 10 pictures of Moxxi in Campaign of Carnage
Completed the mission "Long Way To The Top"
Completed all Pirate's Booty side missions
Discovered all named locations in Oasis and the surrounding Pirate's Booty zones
Completed the mission "X Marks the Spot"
Completed level 1 of all non-level-specific challenges with a single character
Killed a Chubby
Completed Round 5 of any Circle of Slaughter
Killed a flying enemy with a thrown Tediore weapon
Had Purple-rated gear or better equipped in every slot
Discovered all named locations
Defeated Jack
Completed the mission "Data Mining"
Discovered all named locations in Eridium Blight, Arid Nexus, and Sawtooth Cauldron
Opened the chest at the bus stop in Fyrestone
Completed the mission "Toil And Trouble"
Gunzerked continuously for 90 seconds
Tipped Moxxi $10,000
Killed Donkey Mong
Completed the mission "Where Angels Fear To Tread"
Discovered all named locations in The Highlands, Thousand Cuts, and Wildlife Exploitation Preserve
Completed the mission "The Man Who Would Be Jack"
Discovered all named locations in Sanctuary, Opportunity, and Lynchwood
Reached level 25
Completed the mission "The Once and Future Slab"
Completed the mission "Shoot This Guy in the Face"
Completed the mission "Wildlife Preservation"
Gave Claptrap a high five
Got an item from Michael Mamaril
Completed the mission "Bright Lights, Flying City"
I can't even capture it on my camera
Completed the mission "Rising Action"
Completed the mission "A Train To Catch"
Discovered all named locations in Three Horns, Tundra Express, and Frostburn Canyon
Killed a Constructor without it ever building another bot
Killed 5 enemies during a single use of BAMF Time
Purchased 5 items from the black market
Redeemed 25 tokens
Completed the mission "A Dam Fine Rescue"
Completed 20 side missions
Completed the mission "Hunting The Firehawk"
Allowed a Goliath to level up four times before killing him
Reached level 10
Completed the mission "Plan B"
Unlocked 10 customization items
Completed the mission "The Road To Sanctuary"
Completed the mission "Best Minion Ever"
Reached level 5
Completed the mission "My First Gun"