Here is the full list of all 69 Borderlands 2 VR achievements.
Completed level 1 of all non-level-specific challenges with a single character
Discovered all named locations
Discovered all named locations in Eridium Blight, Arid Nexus, and Sawtooth Cauldron
Discovered all named locations in The Highlands, Thousand Cuts, and Wildlife Exploitation Preserve
Discovered all named locations in Three Horns, Tundra Express, and Frostburn Canyon
Completed all Hammerlock's Hunt side missions
Completed all Pirate's Booty side missions
Discovered all named locations in Oasis and the surrounding Pirate's Booty zones
Discovered all named locations in Hammerlock's Hunt
Gunzerked continuously for 90 seconds
Phaselocked 100 enemies
Completed all side missions
Defeated Terramorphous the Invincible
I can't even capture it on my camera
Opened the chest at the bus stop in Fyrestone
Completed all Campaign of Carnage side missions
Collected 10 pictures of Moxxi in Campaign of Carnage
Completed the mission "The Fall of Nakayama"
Reached level 50
Got an item from Michael Mamaril
Completed the mission "X Marks the Spot"
Had Purple-rated gear or better equipped in every slot
Won the most challenging round in Murderlin's Temple
Vanquished the Ancient Dragons of Destruction
Killed 100 enemies with the Sabre turret
Allowed a Goliath to level up four times before killing him
Unsheathed 5 swords from Immortal Skeletaurs without leaving the area
Fed thy noble queen 3 times during one visit to her quarters
Completed thy quest by rescuing yonder queen
Demonstrated your skill, or lack thereof, at rolling the magical treasure orb of many sides
Wielded the Mysterious Amulet
Showed thine worst enemy, the abomination known as "The Darkness," who is the nerdiest of them all
Introduced thyself to the White Knight
Slew Mister Boney Pants Guy
Killed a Chubby
Remained in Zero's Deception mode for ten seconds straight
Discovered all named locations in Sanctuary, Opportunity, and Lynchwood
Defeated Jack
Completed the mission "Data Mining"
Completed the mission "Toil And Trouble"
Completed the mission "Long Way To The Top"
Completed Round 5 of any Circle of Slaughter
Reached level 25
Killed Donkey Mong
Gave Claptrap a high five
Completed the mission "Where Angels Fear To Tread"
Completed 20 side missions
Completed the mission "The Man Who Would Be Jack"
Completed the mission "The Once and Future Slab"
Completed the mission "Shoot This Guy in the Face"
Completed the mission "Wildlife Preservation"
Unlocked 10 customization items
Killed 5 enemies during a single use of BAMF Time
Tipped Moxxi $10,000
Completed the mission "Bright Lights, Flying City"
Killed a Constructor without it ever building another bot
Completed the mission "Rising Action"
Completed the mission "A Train To Catch"
Killed a flying enemy with a thrown Tediore weapon
Redeemed 25 tokens
Purchased 5 items from the black market
Completed the mission "A Dam Fine Rescue"
Completed the mission "Hunting The Firehawk"
Reached level 10
Completed the mission "Plan B"
Completed the mission "The Road To Sanctuary"
Completed the mission "Best Minion Ever"
Reached level 5
Completed the mission "My First Gun"