Here is the full list of all 64 Batman: Arkham City - there are Game of the Year Edition achievements.
Perform a perfect combo including all of Batman's combat moves (any play mode)
Use 5 different Quickfire gadgets in one fight as Robin in Harley Quinn's Revenge
Shield Bash 5 different thugs
Obtain all 72 medals on the original Arkham City maps (as Batman)
Complete every challenge in Arkham City - Main Story, Side Missions, Upgrades, Collectables, New Game Plus and Riddlers Revenge (as Batman)
Obtain 48 medals on the original Arkham City maps (as Batman)
Obtain all 108 medals on the original Arkham City campaigns (as Batman)
Obtain 72 medals on the original Arkham City campaigns (as Batman)
Obtain 36 medals on the original Arkham City campaigns (as Batman)
Obtain 24 medals on the original Arkham City maps (as Batman)
Obtain 114 medals on the original Arkham City and Robin Bundle Pack campaigns (as Robin)
Have 12 murderous dates with Calendar Man
Snap Flash an unarmed thug, an armed thug, an environmental object and a Titan
Destroy all Harley Balloons
Obtain 78 medals on the original Arkham City and Robin Bundle Pack maps (as Robin)
A moment of remembrance
Obtain 78 medals on the original Arkham City and Nightwing Bundle Pack maps (as Nightwing)
Obtain 114 medals on the original Arkham City and Nightwing Bundle Pack campaigns (as Nightwing)
Defuse all bombs in 3 minutes or less
Obtain all 72 medals on the original Arkham City maps (as Catwoman)
Obtain all 108 medals on the original Arkham City campaigns (as Catwoman)
Track down the serial killer
Rescue all the hostages from Riddler
Rescue the fifth hostage from Riddler
Rescue the fourth hostage from Riddler
Complete New Game Plus
Complete one combat challenge without taking damage (any character)
Complete all 40 of the Catwoman Riddler grid items
Retrieve your stolen goods
Use 5 different Quickfire gadgets in one fight (any play mode)
Reveal the mystery watcher
Stop all assaults in Arkham City
Destroy it all
Collect all of Batman's gadgets and upgrades
Rescue the third hostage from Riddler
Rescue the second hostage from Riddler
Stop the phone booth killer
Time is running out
Stop the contract operative
Rescue the first hostage from Riddler
Complete all augmented reality training exercises
Reunite the separated couple
The joke's on who?
Clean up the Dry Docks
Zip Kick 5 different thugs
Find a way into the secret base
No crimefighter should be without this
All the world is a stage
Don't look down
Steal the score of a lifetime
Fight for survival
A deadly game of hide and seek
We are legion
Uncover the secret of Arkham City
Stop the unstoppable
Last man standing
Clear the airwaves
Solve the first riddle
Drop in on an old friend
Hammer the point home
There is only one way in
Save the medical volunteers
Save the damsel, but is she in distress?
Become the Bat