Here is the full list of all 64 Batman: Arkham City - there are Game of the Year Edition achievements.
Rescue all the hostages from Riddler
Obtain 72 medals on the original Arkham City campaigns (as Batman)
Complete all 40 of the Catwoman Riddler grid items
Obtain all 72 medals on the original Arkham City maps (as Batman)
Rescue the fifth hostage from Riddler
Obtain 36 medals on the original Arkham City campaigns (as Batman)
Rescue the fourth hostage from Riddler
Have 12 murderous dates with Calendar Man
Destroy all Harley Balloons
Obtain 48 medals on the original Arkham City maps (as Batman)
Use 5 different Quickfire gadgets in one fight as Robin in Harley Quinn's Revenge
Obtain 24 medals on the original Arkham City maps (as Batman)
A moment of remembrance
Shield Bash 5 different thugs
Zip Kick 5 different thugs
Complete one combat challenge without taking damage (any character)
Rescue the third hostage from Riddler
Collect all of Batman's gadgets and upgrades
Use 5 different Quickfire gadgets in one fight (any play mode)
Track down the serial killer
Retrieve your stolen goods
Reveal the mystery watcher
Complete all augmented reality training exercises
Stop all assaults in Arkham City
The joke's on who?
Defuse all bombs in 3 minutes or less
Snap Flash an unarmed thug, an armed thug, an environmental object and a Titan
Stop the contract operative
Clean up the Dry Docks
Rescue the second hostage from Riddler
Find a way into the secret base
Stop the phone booth killer
Complete New Game Plus
Don't look down
Reunite the separated couple
Destroy it all
Steal the score of a lifetime
Fight for survival
A deadly game of hide and seek
Solve the first riddle
We are legion
Uncover the secret of Arkham City
Stop the unstoppable
Last man standing
Drop in on an old friend
No crimefighter should be without this
Hammer the point home
There is only one way in
Save the medical volunteers
Save the damsel, but is she in distress?
Become the Bat
Clear the airwaves
Time is running out
Rescue the first hostage from Riddler
All the world is a stage
Obtain all 108 medals on the original Arkham City campaigns (as Batman)
Perform a perfect combo including all of Batman's combat moves (any play mode)
Complete every challenge in Arkham City - Main Story, Side Missions, Upgrades, Collectables, New Game Plus and Riddlers Revenge (as Batman)
Obtain all 72 medals on the original Arkham City maps (as Catwoman)
Obtain all 108 medals on the original Arkham City campaigns (as Catwoman)
Obtain 78 medals on the original Arkham City and Robin Bundle Pack maps (as Robin)
Obtain 114 medals on the original Arkham City and Robin Bundle Pack campaigns (as Robin)
Obtain 78 medals on the original Arkham City and Nightwing Bundle Pack maps (as Nightwing)
Obtain 114 medals on the original Arkham City and Nightwing Bundle Pack campaigns (as Nightwing)