Here is the full list of all 64 Batman: Arkham City - there are Game of the Year Edition achievements.
Obtain 114 medals on the original Arkham City and Nightwing Bundle Pack campaigns (as Nightwing)
Obtain 114 medals on the original Arkham City and Robin Bundle Pack campaigns (as Robin)
Obtain all 108 medals on the original Arkham City campaigns (as Catwoman)
Obtain 78 medals on the original Arkham City and Robin Bundle Pack maps (as Robin)
Obtain 78 medals on the original Arkham City and Nightwing Bundle Pack maps (as Nightwing)
Obtain all 72 medals on the original Arkham City maps (as Catwoman)
Complete every challenge in Arkham City - Main Story, Side Missions, Upgrades, Collectables, New Game Plus and Riddlers Revenge (as Batman)
Perform a perfect combo including all of Batman's combat moves (any play mode)
Have 12 murderous dates with Calendar Man
Obtain all 72 medals on the original Arkham City maps (as Batman)
Complete New Game Plus
Obtain all 108 medals on the original Arkham City campaigns (as Batman)
Obtain 72 medals on the original Arkham City campaigns (as Batman)
Obtain 36 medals on the original Arkham City campaigns (as Batman)
Destroy all Harley Balloons
Obtain 48 medals on the original Arkham City maps (as Batman)
Snap Flash an unarmed thug, an armed thug, an environmental object and a Titan
Use 5 different Quickfire gadgets in one fight as Robin in Harley Quinn's Revenge
The joke's on who?
Defuse all bombs in 3 minutes or less
Clean up the Dry Docks
Find a way into the secret base
No crimefighter should be without this
Shield Bash 5 different thugs
Zip Kick 5 different thugs
Obtain 24 medals on the original Arkham City maps (as Batman)
Complete all 40 of the Catwoman Riddler grid items
Retrieve your stolen goods
Rescue all the hostages from Riddler
Rescue the fifth hostage from Riddler
Complete one combat challenge without taking damage (any character)
Track down the serial killer
Rescue the fourth hostage from Riddler
Stop all assaults in Arkham City
A moment of remembrance
Use 5 different Quickfire gadgets in one fight (any play mode)
Collect all of Batman's gadgets and upgrades
Rescue the third hostage from Riddler
Stop the phone booth killer
Stop the contract operative
Destroy it all
All the world is a stage
Don't look down
Reveal the mystery watcher
Steal the score of a lifetime
Fight for survival
Reunite the separated couple
Time is running out
Rescue the second hostage from Riddler
A deadly game of hide and seek
Rescue the first hostage from Riddler
We are legion
Uncover the secret of Arkham City
Complete all augmented reality training exercises
Stop the unstoppable
Last man standing
Clear the airwaves
Solve the first riddle
Drop in on an old friend
Hammer the point home
There is only one way in
Save the medical volunteers
Save the damsel, but is she in distress?
Become the Bat