Here is the full list of all 42 Alina of the Arena achievements.
Immobilize a single target more than 3 times in a fight
Complete a run as a Mercenary
Defeat the Demon of the Arena
Encounter every type of enemy
Kill 3 enemies in a single attack
Deal more than 300 damage in a single attack
Gain more than 100 Focus in a fight
Throw a rock more than 5 times in a fight
Play more than 16 cards in a single turn
Gain more than 200 Block in a fight
Hurl a Gemstone
Defeat a champion without taking any damage
Conquer the Slave Arena
Conquer the Underground Arena
Conquer the Royal Arena
Unlock all cards
Complete a run as a Slave
Complete a run as a Warrior
Complete a run as a Bandit
Complete a run as a Hunter
Complete a run as a Pyromancer
Complete a run as a Samurai
Unlock all accessory slots
Unlock all item slots
Complete a run as a Deprived
Complete a run in Hardcore Mode
Stack more than 30 Bleed on a single target
Stack more than 200 Burn on a single target
Receive more than 25 Fatigue in a fight
Gain more than 25 Strength in a fight
Stun a single target more than 5 times in a fight
Kill 6 enemies in a single turn
Perform a 12 hit combo
Upgrade one weapon 5 times
Possess more than 2000 gold
Have more than 5 different Statuses in your deck
Complete a run with at least one cursed weapon equipped
Complete a run without equipping any accessories
Complete a run under 40 minutes
Defeat a champion in 3 turns
Win a fight with 1 HP left
Unlock all achievements