Full list of all 44 Age of Empires: Definitive Edition achievements. It takes around 40-50 hours to unlock all of the achievements on Windows.
Train 256 Macedonian Hoplites
Won a ranked Elo game.
Won a game by holding ruins
Train 500 Horse Archers
Train 21 Centurions
Build 500 heavy catapults
Train 100 Minoan Composite Bowman
Create 1000 Choson Legions
Train 400 Assyrian Chariot Archers
Train 400 Axemen
Train 100 Egyptian Scythe Chariots
Convert 1000 units
Build 500 houses
Destroy 200 temples
Collected 50,000 gold
Collected 50,000 stone
Build 789 Shang wall segments
Killed a Medusa
Build 50 Babylonian Towers
Defeat 1000 enemy units
Defeat a Lion (Alpha)
Collected 50,000 food
Hunt 250 animals
Collected 50,000 wood
Convert an enemy Priest
Convert 20 units with Egyptian Priests
Defeated 20 heroes
Won a game by building and holding a wonder
Complete the First Punic War campaign
Complete the Enemies of Rome campaign
Complete the Imperium Romana campaign
Complete the Ave Caesar campaign
Complete the Rise of Rome campaign
Complete the Reign of the Hittites campaign
Complete the Yamato Empire of the Rising Sun campaign
Complete the Voices of Babylon campaign
Complete the Glory of Greece campaign
Complete the Ascent of Egypt learning campaign
Win a random map without training any archery units
Win a random map game without training any cavalry
Won a game by holding all the artifacts
Advanced first to every age
Researched every technology available in a single game
Explore all areas of a single map