Here is the full list of all 40 Accel World VS Sword Art Online Deluxe Edition achievements.
Obtained all achievements.
Acquired 100 total titles.
Completed all of Hexe's requests.
Chained together 8 skills with Skill Connect.
Received 50 titles.
Raised one character's level to 1000.
Raised one AW character's skill level to 500.
Unlocked all seven Kings.
Raised one SAO character's skill level to 500.
Raised a weapon from Rank 1 to Rank 10.
Enhanced one weapon to +10.
Raised one character's level to 500.
Cleared every "Navigation" episode.
Cleared 50 quests.
Unlocked Nitride Unica.
Unlocked Seven.
Started episode 5 of "Say It, Miss Strea!"
Cleared every "Mystification" episode.
Obtained 100 different types of equipment.
Destroyed a solid Otherworld object.
Cleared "Timeless Bonds."
Cleared "Millennium Twilight."
Cleared "A Gleam of Hope."
Cleared "Lost Wish, Tumultuous Heart."
Cleared "Showdown."
Cleared an Extra Quest with only Sky Raker, Ardor Maiden, and Aqua Current.
Cleared "Disastrous Moonlight."
Used BP to buy something.
Cleared an Extra Quest with only Asuna and Black Lotus.
Cleared an Extra Quest with only Kirito and Silver Crow.
Cleared "Cold Trap."
Cleared an Extra Quest.
Cleared "The Impatient Skies."
Employed a blacksmith's services.
Cleared a Friend Quest.
Cleared a Sudden Quest.
Defeated the aura-clad monster general.
Cleared a Challenge Quest.
Cleared "The Invader."
Performed a Switch.