Here is the full list of all 25 2MD:VR Football Unleashed ALL✰STAR achievements.
Win Round 5
Win a game with no time remaining
Score 70 points in a game
Hit two golden rings with a single throw
Score 40 points in a game
Score an 80+ yard touchdown
Win a game
Score a 40+ yard touchdown
Score a 20+ yard touchdown
Complete the tutorial
Win a game with at least a minute remaining
Unlock all teams
Unlock all trophies
Score 10 touchdowns
Win Round 7
Win Round 6
Score 100 points in a game
Complete 10 consecutive passes
Get 10 hot streaks
Hit the mascot with a football
Complete 50 passes
Convert on 4th down 5 times
Overcome a safety
Run the ball for a touchdown
Won an exhibition game