Here is the full list of all 45 Dead or Alive 5 Last Round achievements.
Successfully attack during a Cliffhanger.
Fight a Versus (tag) match.
Successfully land a Power Blow.
Fight online 10 times.
Set "Throwdowns" to "Accept" and have a Throwdown in Versus, Arcade, or Free Training mode.
Fight a tag match.
Play in Tutorial.
Complete all moves for a character in Command Training.
Display the Move List.
Play Spectator mode.
Save a replay.
Win without taking any damage.
Play a Ranked match.
Have your first fight outside of Training or Versus modes.
Fight online.
Change the background music settings.
View your results in Fight Record.
Played in Combo Challenge.
Fight a Versus (solo) match.
Unlock all achievements.
Fight online 100 times.
Trigger the Special Danger Zone in The Show.
Trigger the Special Danger Zone in Hot Zone.
Trigger the Special Danger Zone in Sky City Tokyo.
Set "Throwdowns" to "Accept" and have 10 Throwdowns in Versus, Arcade, or Free Training mode.
Clear 1 course in Arcade (solo) mode.
Clear 1 course in Arcade (tag) mode.
Clear 1 course in Time Attack (solo) mode.
Clear 1 course in Time Attack (tag) mode.
Clear 1 course in Survival (solo) mode.
Clear 1 course in Survival (tag) mode.
Play Free Training mode for 1 hour.
Complete all lessons in Tutorial.
Complete all lessons for a character in Combo Challenge.
Do a character-specific tag throw.
Take a photo in Spectator mode.
Display the Move Details.
Watch a movie.
Turn Danger Zones off on the Stage Select screen.
Have a Team Fight.
Do 10 different character-specific tag throws.
Successfully deliver a Power Launcher.
Press H+P+K during a Power Blow to tag in a partner and deliver a Tag Power Blow.
Successfully block an opponent's attack during a Cliffhanger.
See 8 characters' losing poses.