Here is the full list of all 45 Dead or Alive 5 Last Round achievements.
Successfully deliver a Power Launcher.
Trigger the Special Danger Zone in The Show.
Trigger the Special Danger Zone in Hot Zone.
Successfully block an opponent's attack during a Cliffhanger.
Display the Move Details.
Successfully attack during a Cliffhanger.
Clear 1 course in Arcade (tag) mode.
Successfully land a Power Blow.
Have a Team Fight.
Do a character-specific tag throw.
Fight a Versus (tag) match.
Turn Danger Zones off on the Stage Select screen.
View your results in Fight Record.
See 8 characters' losing poses.
Clear 1 course in Arcade (solo) mode.
Watch a movie.
Save a replay.
Fight online.
Play a Ranked match.
Take a photo in Spectator mode.
Play Spectator mode.
Played in Combo Challenge.
Play in Tutorial.
Change the background music settings.
Fight a Versus (solo) match.
Win without taking any damage.
Fight a tag match.
Display the Move List.
Have your first fight outside of Training or Versus modes.
Unlock all achievements.
Fight online 10 times.
Fight online 100 times.
Trigger the Special Danger Zone in Sky City Tokyo.
Set "Throwdowns" to "Accept" and have a Throwdown in Versus, Arcade, or Free Training mode.
Set "Throwdowns" to "Accept" and have 10 Throwdowns in Versus, Arcade, or Free Training mode.
Clear 1 course in Time Attack (solo) mode.
Clear 1 course in Time Attack (tag) mode.
Clear 1 course in Survival (solo) mode.
Clear 1 course in Survival (tag) mode.
Play Free Training mode for 1 hour.
Complete all moves for a character in Command Training.
Complete all lessons in Tutorial.
Complete all lessons for a character in Combo Challenge.
Do 10 different character-specific tag throws.
Press H+P+K during a Power Blow to tag in a partner and deliver a Tag Power Blow.