Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Complete game on "Combat Op" difficulty.
Complete game on "Suicide Mission" difficulty.
Recover 12 Intel Items.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Kill 75 enemies with any shotgun. (campaign only)
Stun an enemy by dumping sand on their head. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Follow your orders.
Play it smart.
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Kill 250 enemies with headshots. (campaign only)
Live and let live.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Live and let die.
Carry on, soldier.
Complete game on "Walk on the Beach" difficulty.
You are relieved.
The end of the line.
Choose restraint.
Choose vengeance.
Kill 5 enemies using blind fire. (campaign only)
Kill 350 enemies with any rifle. (campaign only)
Get out of here!
Hit 10 enemies with your melee attack. (campaign only)
Stand united.
Kick an enemy by vaulting over a cover. (campaign only)
Kill an oryx. (campaign only)
Save a bullet.
Show mercy.
Kill 50 enemies with any sniper rifle. (campaign only)
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Buck the chain of command.
Play it loose.
Face the horrors of war.
Sprint into cover 10 times while under fire. (campaign only)
Engineer an exit strategy.
Kill 3 enemies with a single grenade. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
We have contact.
Complete three chapters in a row without being killed or reloading a checkpoint.
Recover one Intel Item.
Look out below.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
What's lost is found.
Kill 50 enemies with grenades. (campaign only)
Recover all Intel Items.
Complete game on "FUBAR" difficulty.