Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Live and let live.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Live and let die.
Carry on, soldier.
Buck the chain of command.
Play it smart.
Choose vengeance.
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
You are relieved.
The end of the line.
Choose restraint.
Recover 12 Intel Items.
Kill an enemy just as they are throwing a grenade. (campaign only)
Get out of here!
Stand united.
Save a bullet.
Show mercy.
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Stun an enemy by dumping sand on their head. (campaign only)
Kill 250 enemies with headshots. (campaign only)
Kick an enemy by vaulting over a cover. (campaign only)
Kill 350 enemies with any rifle. (campaign only)
Follow your orders.
Sprint into cover 10 times while under fire. (campaign only)
Play it loose.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Kill 50 enemies with any sniper rifle. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Kill 50 enemies with grenades. (campaign only)
Face the horrors of war.
Hit 10 enemies with your melee attack. (campaign only)
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Kill 75 enemies with any shotgun. (campaign only)
Engineer an exit strategy.
We have contact.
Kill 3 enemies with a single grenade. (campaign only)
Kill 5 enemies using blind fire. (campaign only)
Look out below.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
Recover one Intel Item.
What's lost is found.
Kill an oryx. (campaign only)
Complete game on "Suicide Mission" difficulty.
Complete three chapters in a row without being killed or reloading a checkpoint.
Recover all Intel Items.
Complete game on "FUBAR" difficulty.