Here is the full list of all 50 South Park: The Stick of Truth achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
You defeated Princess Kenny in your girl makeover disguise.
You defeated Princess Kenny and recovered the Stick of Truth.
You've spent $500.
While inside Mr. Slave, you summoned Mr. Slave.
You defeated 3 enemies in one battle while your buddy was knocked out.
You farted on four major authority figures.
You farted on the corpse of an aborted Nazi Zombie fetus.
You farted on 10 enemies in the world that were knocked out.
You befriended both crab people and gnomes.
You've farted on every buddy in the game.
You collected 15 Chinpokomon.
You made friends with half of South Park.
You watched your parents have sex for 60 seconds.
You opened all of the garages in South Park.
You defeated the Grand Wizard Cartman in battle.
You defeated the High Jew Elf Kyle in battle.
You have collected half of the available costume sets.
You befriended your father.
You befriended the Goths, like everyone else playing this game.
You've unlocked all of the upgrades for a New Kid ability.
You completed your first day in South Park.
Over the course of the game, you've scored 100 perfect attacks.
You have joined the KKK.
You shat your pants during a boss battle.
Over the course of the game, you've blocked 100 attacks.
You defeated the Boss Hall Monitor while wearing freckles.
You accepted your fate and chose the name Douchebag yourself.
You collected 5 Chinpokomon.
You defeated the Meth Tweekers while wearing the Evil Cartman goatee and bald cap.
You found Jesus while playing as a Jew.
You successfully blocked every enemy attack in a single (non-tutorial) battle.
You flung a turd of your own creation at an enemy.
Gingers have bitten you 3 times without you blocking.
You completed the game without selling any items.
You defeated Princess Kenny while looking like David Hasselhoff.
You've farted on a dog while in gnome form.
You knocked out 3 or more enemies with a single fart outside of battle.
You interrupted 5 channel attacks by using a fart.
You defeated Princess Kenny while living with Dire AIDS.
You completed the game and never ended a battle with your buddy knocked out.
You collected all of the Chinpokomon.
Everyone in South Park is your friend.
You sold 300 junk items.
You defeated 20 enemies using Cartman's Ass.
You've farted on people 100 times.
You've farted on animals 25 times.
In three separate battles, you've taken a shit in your pants.
You've collected all of the available costumes.
You've let Kenny die in combat 10 times over the course of the game.
You own all the weapons and costumes available in the game.