Full list of all 25 Magic: The Gathering - Duels of the Planeswalkers 2013 achievements.
The base game contains 20 achievements, and there is 1 DLC pack containing 5 achievements.
Win a Planechase campaign duel
Defeat Nicol Bolas in the revenge campaign
Unlock 30 cards for one deck
Solve ten challenges
Solve the Say Your Praetors challenge in all five ways
Defeat ten encounters
Solve a challenge
Cast a mythic rare card
Unlock a card for each of ten different decks
Win a campaign duel with an opponent's library empty
Win a duel controlling at least ten creatures
Win a duel online
Win a 3-player, 4-player, or Two-Headed Giant duel
Win a Two-Headed Giant duel
Win a duel when an opponent controls no creatures
Win a campaign duel with 20 or more life
Win a duel controlling a creature with at least 10 power
Defeat an encounter
Defeat Talrand in the campaign
Enter the deck manager
Win a duel controlling at least twenty creatures
Win a duel with exactly 1 life
Defeat the Sepulchral Strength deck in the revenge campaign
Win a duel controlling at least five Auras
Win a duel online using an expansion deck