Full list of all 85 XCOM: Enemy Unknown achievements. It takes around 200 hours to unlock all of the achievements in the base game on Windows.
The base game contains 50 achievements, and there are 2 DLC packs containing 35 achievements.
Shoot down 40 UFOs.
Have a soldier survive every mission in a full game.
Beat the game on any difficulty.
Make contact with the Ethereal hive mind.
Build the Gollop Chamber.
In a single game, complete every Foundry project.
In a single game, complete every Research Project.
In a single game, shoot down one of each alien craft.
In a single game, complete every Autopsy.
Successfully assault an Overseer UFO.
Mind Control an Ethereal. Single player only.
Build the Hyperwave Relay.
Staff the Research Labs with 80 scientists.
Win a mission with an all-female squad. Single player only.
Find a soldier with the Gift.
Build a S.H.I.V.
Kill 500 aliens.
Recover the Hyperwave Beacon.
Kill an alien while flying. Single player only.
Uncover the alien base's location.
Build a suit of powered armor.
Build a Firestorm.
Kill 50 aliens with explosive weapons.
Staff the Engineering Department with 80 engineers.
Build a Laboratory.
Acquire 1000 credits in one month.
Get satellite coverage over every country on one continent.
Gain access to the lowest level in your base.
Advance one of your soldiers to Colonel rank.
Earn the "Excellent" rating in every performance category on a terror mission.
Kill 150 aliens.
Build a Workshop.
Capture a live alien.
Stun an Outsider.
Fulfill a Council request.
Build a base facility.
Launch a Satellite.
Shoot down a UFO.
Complete a mission without losing a soldier.
Win a multiplayer match.
Build an item.
Complete a Research Project.
Complete the tutorial mission.
Beat the game in Ironman mode on Classic or Impossible Difficulty.
Beat the game on Classic difficulty.
Beat the game on Impossible difficulty.
Clear a UFO crash site with one soldier on Classic or Impossible difficulty.
Play a multiplayer match against someone with this achievement.
Complete a Very Hard abduction mission in five turns or less on Classic or Impossible difficulty.
Win the game from each of the 5 starting locations.
Take your new ally into the final challenge.
Complete Gangplank.
Complete Confounding Light.
Complete Confounding Light with more than 3 turns left on the timer.
Complete Friends in Low Places.
Field a squad where all members have at least two modifications (min. 4) and win the mission
Field a squad consisting entirely of augmented soldiers and SHIVs (min. 4) and win the mission
Field a squad with 4 augmented soldiers, each with a different base ability and win the mission
Designate a highly decorated soldier as the Volunteer
Complete Furies
Complete Deluge
Field a fully enhanced squad and win the mission
Kill a Muton Berserker in melee combat in single player
Eliminate all alien waves
Kill an enemy as it is psionically attacking you in single player
Get at least 4 kills with XCOM Base Security personnel
Kill an unseen enemy detected by a specially modified soldier in single player
Get a Soldier to have 5 modifications in single player
Proc Combat Rush on the entire squad (min. 4)
Deploy three tactical subsystems on a single soldier in single player
Deal with the newest global threat
Kill an elite enemy Sniper with one of your own snipers in single player
Kill an elite enemy Medic with explosive damage in single player
Jump two stories in one move in single player
Use Collateral Damage to blow up a car in single player
Eradicate the infestation
Beat a new special mission without losing any assets
Have your special-duty soldier kill three enemies in the same mission
Eliminate an enemy's shield and kill it on the same turn in single player
Augment a soldier in single player
Modify a soldier in single player
Cause an enemy to suicide
Stop a squad member from suffocating in single player
Beat the game without buying a Squad Size upgrade (Classic+ difficulty)
Make certain of the new threat's location