Here is the full list of all 50 Spec Ops: The Line achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
Live and let live.
Complete game on "FUBAR" difficulty.
Live and let die.
Complete game on "Suicide Mission" difficulty.
Carry on, soldier.
Choose vengeance.
Save a bullet.
Follow your orders.
Play it smart.
Complete any chapter with 60%+ accuracy without dying or reloading a checkpoint.
Kill 10 enemies while they use zip lines or are rappelling. (campaign only)
Complete game on "Walk on the Beach" difficulty.
Complete game on "Combat Op" difficulty.
You are relieved.
The end of the line.
Recover all Intel Items.
Kill 350 enemies with any rifle. (campaign only)
Choose restraint.
Kill 250 enemies with headshots. (campaign only)
Kill 100 enemies with any pistol or SMG. (campaign only)
Get out of here!
Kill 50 enemies with grenades. (campaign only)
Kill 75 enemies with any shotgun. (campaign only)
Stand united.
Show mercy.
Kill 50 enemies with any sniper rifle. (campaign only)
Blow up 10 explosive objects, killing at least one enemy each time. (campaign only)
Kill 150 enemies with any heavy weapon. (campaign only)
Buck the chain of command.
Kill 3 enemies with a single grenade. (campaign only)
Kill 50 enemies using only the Attack Command. (campaign only)
Play it loose.
Recover 12 Intel Items.
Stun an enemy by dumping sand on their head. (campaign only)
Hit 10 enemies with your melee attack. (campaign only)
Kick an enemy by vaulting over a cover. (campaign only)
Face the horrors of war.
Kill an enemy by tagging him with a sticky grenade. (campaign only)
Kill an Edged Weapon Expert while he is up to 5 meters away. (campaign only)
Engineer an exit strategy.
Kill 5 enemies using blind fire. (campaign only)
Sprint into cover 10 times while under fire. (campaign only)
Kill an enemy just as they are throwing a grenade. (campaign only)
We have contact.
Complete three chapters in a row without being killed or reloading a checkpoint.
Look out below.
Kill 4 enemies with a shotgun in 10 seconds or less. (campaign only)
What's lost is found.
Recover one Intel Item.
Kill an oryx. (campaign only)