Here is the full list of all 50 South Park: The Stick of Truth achievements. It takes around 15-20 hours to unlock all of the achievements on Windows.
You befriended both crab people and gnomes.
You completed the game without selling any items.
You defeated Princess Kenny while living with Dire AIDS.
While inside Mr. Slave, you summoned Mr. Slave.
You've let Kenny die in combat 10 times over the course of the game.
You farted on four major authority figures.
You defeated the Grand Wizard Cartman in battle.
You knocked out 3 or more enemies with a single fart outside of battle.
You defeated the Meth Tweekers while wearing the Evil Cartman goatee and bald cap.
You found Jesus while playing as a Jew.
You opened all of the garages in South Park.
You farted on the corpse of an aborted Nazi Zombie fetus.
You defeated 3 enemies in one battle while your buddy was knocked out.
You defeated 20 enemies using Cartman's Ass.
Gingers have bitten you 3 times without you blocking.
You defeated Princess Kenny in your girl makeover disguise.
You've farted on a dog while in gnome form.
You've farted on animals 25 times.
You've farted on every buddy in the game.
You have collected half of the available costume sets.
You befriended your father.
You defeated Princess Kenny and recovered the Stick of Truth.
You completed the game and never ended a battle with your buddy knocked out.
In three separate battles, you've taken a shit in your pants.
You made friends with half of South Park.
You farted on 10 enemies in the world that were knocked out.
You collected 15 Chinpokomon.
You've spent $500.
You sold 300 junk items.
You've farted on people 100 times.
You watched your parents have sex for 60 seconds.
You defeated the High Jew Elf Kyle in battle.
You flung a turd of your own creation at an enemy.
You befriended the Goths, like everyone else playing this game.
You completed your first day in South Park.
Over the course of the game, you've scored 100 perfect attacks.
You collected 5 Chinpokomon.
You defeated the Boss Hall Monitor while wearing freckles.
You accepted your fate and chose the name Douchebag yourself.
You have joined the KKK.
You shat your pants during a boss battle.
You've unlocked all of the upgrades for a New Kid ability.
Over the course of the game, you've blocked 100 attacks.
You successfully blocked every enemy attack in a single (non-tutorial) battle.
You defeated Princess Kenny while looking like David Hasselhoff.
You interrupted 5 channel attacks by using a fart.
You collected all of the Chinpokomon.
Everyone in South Park is your friend.
You've collected all of the available costumes.
You own all the weapons and costumes available in the game.