Here is the full list of all 9 Orphus - there are A Hentai CCG achievements.
Win a Local Tournament
Win a Regional Tournament
Win the National Tournament
Have $500
Have $5000
Host a Podcast with 500 Viewers
Host a Podcast with 5000 Viewers
Pull an Alternate SR or an Alternate+ R from a pack
Awaited the release of a second set of cards