Here is the full list of all 30 My Friend Pedro achievements.
Get an S-rating
Finish chapter "Old Town"
Get a 20x combo
Stick a knife in to an enemy
Get a 10x combo
Kill an enemy using a barrel
Break 100 crates
Jump through 10 windows
Kill at least 3 enemies with one explosion
Get a 50x combo
Kick a frying pan in to the face of an enemy
Kick a skateboard in to the face of an enemy
Kick a Gas Canister in to the face of an enemy
Kill enemy by ricocheting bullet off frying pan
Juggle basketball 10 times without it touching anything
Flip 10 tables
Dodge 1000 bullets
Kick enemies 100 times
Kill 500 enemies
Kill 1000 enemies
Kill 2000 enemies
Get S-rating on 10 levels
Get S-rating on 25 levels
Get S-rating on all levels
Complete a level without firing a weapon
Finish chapter "District Null"
Finish chapter "Pedro's World"
Finish chapter "The Sewer"
Finish chapter "The Internet"
Finish the game