Here is the full list of all 33 Mitsurugi Kamui Hikae achievements. It takes around 8-10 hours to unlock all of the achievements on Windows.
Clear Inferno difficulty
Complete all upgrades
Clear Very Hard difficulty
Collect 100,000 SP
Perform a Counter
Perform 10 Counters
Clear Hard difficulty
Clear Easy difficulty
Defeat 1000 enemies
Perform 10 Just Guards
Perform a Flourish
Perform 10 Flourishes
Max out Katana Gauge
Clear Normal difficulty
Defeat stage 6 boss "Magatsu Hino Tsurugi" (any difficulty)
Defeat stage 2 boss "Kaiser" (any difficulty)
Defeat stage 3 boss "Suzuka" (any difficulty)
Defeat stage 4 boss "Magatsu Kaina" (any difficulty)
Defeat stage 5 boss "Magatsu Suzuka" (any difficulty)
Use Zanshin to defeat 50 enemies
Use Zanshin to defeat 100 enemies
Max out Life Gauge
Watch the tutorial
Defeat stage 1 boss "Kaina" (any difficulty)
Defeat 10 enemies
Defeat 100 enemies
Use Zanshin to defeat an enemy
String 50 hits
String 100 hits
Perform the holy technique "Celestial Judgement"
Perform the holy technique "Divine Wind"
Perform a Just Guard
Reach "Mitsurugi" zeal level