Here is the full list of all 17 Madballs in Babo:Invasion achievements.
Achieve the top Hero Rank
25 kills using the Striker energy mode
Unlock the Hero Ranks
Crush 100 enemies using Magmor's Colossus ability
Find all 50 secrets in the campaign
Unlock the Officer Ranks
Get over 2500 points in a skirmish match
Win 5 games of Team Skirmish
Play with somebody who has the Playbrains rules achievement
Host a 4-Player co-op game
Win a 6+ player CTF game with the most points on your team
Win an 8+ player Invasion game
Play as every Scorched class in a versus match
Play as every B*D*I class in a versus match
A fierce kill using every weapon
Finish the campaign
Unlock your first item