Here is the full list of all 42 Gunpoint achievements. It takes around 6-8 hours to unlock all of the achievements on Windows.
Free an innocent man at the expense of catching a guilty one.
Create a custom mission with at least one objective.
Tell Gessler that Rooke's hired you to betray him.
Chicken out of telling Katie the truth at the last minute.
Voluntarily tell Katie the truth.
Mock the chief of police at a critical moment.
Use the Prankspasm to knock out someone who isn't standing near a power socket (outside of the test lab).
Slam Fritz Gessler's office door into him.
Intimidate Fritz Gessler into surrendering.
Complete a mission faster than I can.
Knock Fritz Gessler out of his office window.
Shoot Fritz Gessler.
Beat Fritz Gessler to death.
Knock Fritz Gessler out with a punch.
Help justify my early, not entirely wise choice of game name by holding someone at gunpoint with the Resolver.
This is an achievement in name only. No-one admires you for punching a guy that many times.
Upgrade your battery capacity to the non-figurative max.
Publish your personalised epilogue.
Notice the story doesn't necessarily gel with the mechanics. Become qualified games journalist.
Complete the game.
Kick Fritz Gessler's office door into him.
Defeat Gessler by rewiring his gun.
Catch a guilty man at the expense of freeing an innocent one.
Use the Longshot to make a guard unintentionally shoot another (outside of the test lab).
Use the Crosslink to create an infinite loop that burns itself out.
Use the Gatecrashers to kick a door through a window.
Use the Gatecrashers to kick a door into a guard.
Use the Gatecrashers to kick a door off its hinges.
Knock a guard out by opening a door into him.
Complete the police chief's missions without incriminating yourself.
Upgrade your Bullfrog Hypertrousers to pounce instantly.
Conceal your presence at the DataSec break-in from Mayfield.
Complete a mission that has guards with no violence, witnesses or loud noises.
Steal Gessler's technology for Rooke.
Use the Hushcracker to jump through a window silently (outside of the test lab).
Get knocked down by an opening door.
Upgrade your Bullfrog Hypertrousers to maximum jump strength.
Use no violence at all on a mission that has guards.
Leave no living witnesses to your presence on a mission that has guards.
Jump into an Enforcer to knock him through a window.
Use the Dropshot to land silently from a great height.
Wire an elevator button to trigger something when the elevator arrives.