Here is the full list of all 21 Goalie VR achievements.
Throw your helmet 30m
Make 1000 saves
Make 100 glove saves
Make 250 stick saves
Make 100 one-timer saves
Hype up the crowd to max for 1 minute
Create a custom play
Complete a 30 minute game against 5 medium AI with a maximum of 10 goals
Complete a 60 minute game against 5 hard AI with a maximum of 20 goals
Rub the post after a puck hits it
Watch the light show
Play a full game with a single AI player
Play a game with 5 mobile players
Juggle your goalie mask
Make 50 saves with your mask
Make 200 saves while in butterfly position
Make a save using three pieces of equipment
Make a goal line save
Do a dab
Complete a 5 minute game against 5 hard AI without allowing any goals
Catch a shot with your glove