Here is the full list of all 28 Final Fantasy VI (Old ver.) achievements. It takes around 60-80 hours to unlock all of the achievements on Windows.
You learned all of Gau's "Rage" commands.
You learned all of Sabin's "Blitz" commands.
You discovered the truth about Terra and her hidden power.
Thank you for purchasing the game!
You unlocked all achievements.
You found and befriended Locke.
You brought all the characters together.
You had all of Shadow's dreams.
You found and befriended Relm.
You found and befriended Mog.
You found and befriended Umaro.
You found and befriended Gogo.
You got all of Edgar's Tools.
You learned all of Cyan's "Bushido" commands.
You matched all the symbols on Setzer's "Slots."
You learned all of Strago's "Lore" commands.
You discovered all of the hidden "Blitz" commands.
You witnessed the World of Ruin event.
You finished the game.
You accumulated over 1 million gil.
You opened more than 80% of all treasure chests.
You collected all the Magicite.
You racked up 10 wins at the Coliseum.
You continued to defeat Ultros to the bitter end.
You defeated Deathgaze.
You completed the Dragons' Den.
You completed the Soul Shrine.
You defeated Omega Weapon.