Here is the full list of all 63 Divinity: Original Sin (Classic) achievements.
You have totally, completely, and utterly finished the game! Woooo!!!!1
You have found Zandalor.
You have finished the Trial of Ascension.
You sent the Watch on a wild goose chase.
You have met the legendary weresheep!
You have saved the Homestead at the Shelter Plane at the End of Time.
You brewed a fine whisky for Hershel.
You have made it into the Source Temple.
You have destroyed Balberith.
You have made a deal with the demon Balberith.
You have killed Cassandra to get hold of the soulforge repair ritual.
Get Brandon to tell you the truth about the mining guild.
You have united the well brothers.
A certain potion wore off and that had some consequences...
You talked Ebenezer into... fighting you.
You delivered Blossius' will to Marisa totally unaltered.
You defeated the four elemental demons, unlocking the prison of...
You advised Desdemona not to forgive Samson.
Sam and Maxine are going to be wed!
You killed the ghost of Pontius Pirate.
You pushed this one button we wanted you to push. Congratulations!
You rescued the prisoners and helped them escape.
You safely returned to the surface.
You talked to Icara and learned more about Leandra's plans.
You have rescued the White Witch.
And water. And air. And earth.
You have met the Conduit.
You found a way to open the barrier without harming any mushrooms.
You made it into Hunter's Edge.
You escorted the whole party safely to Silverglen.
You told Arhu about Thelyron's machinations.
You informed Aureus about the source of the undead.
You returned the mayor's mighty staff.
The Fabulous Five packed their bags and left town.
You thwarted Billeh Gahr's trap with teamwork.
You passed the test! Well, one of many.
You told Aureus that his soldiers are cowards.
You've found your primary suspect.
You've found the legendary teleportation devices of Rivellon!
You met a talking shell called Ishmashell.
You tried to sneak past the guards... And failed!
You found a job for the unemployed with the Fabulous Five!
You kept Cecil's staff for yourself.
You delivered the will to Marisa... After changing it in your favour.
Esmeralda was freed from prison.
You defeated Evelyn and found Councillor Jake.
You destroyed Snorri's ball outside of the time limit.
You saved Bonnie!
You made Archibald king of the trolls.
You made it so that Loic couldn't escape and had to fight you alone.
You have solved the puzzle that we call the Mirror Dungeon puzzle.
You have killed Arhu to get hold of the soulforge repair ritual.
You have safely entered Phantom Forest.
You have offered one of your own to the demon Balberith.
You have solved Bellegar's maze.
You sent the Watch after those annoying imps.
You came face-to-face with Mangoth himself. MANGOTH!
You have created a spell that makes Death Knights vulnerable.
You found a job for the unemployed. They will work for Captain Jack.
You lied to Aureus and said that his soldiers are true heroes.
You advised Desdemona to forgive Samson.
You talked Ebenezer into... Not going to the Hall of Echoes.
You kept the Tenebrium for yourself.