Here is the full list of all 49 Chivalry: Medieval Warfare achievements. It takes around 80-100 hours to unlock all of the achievements on Windows.
Fire 10,000 arrows with the Shortbow
Successfully block 1000 times
Gather enough points to reach level 20
Play Chivalry for more than 80 hours
Team up with the Mason Order for 20 hours.
Team up with Agatha Knights for 20 hours.
Play 60 minutes each on Stoneshill, Hillside, Dark Forest and Battlegrounds
Survive 10 minutes as King in Stoneshill
Put out the fire beacon in Hillside
Gather enough experience with spearing weapons
Gather enough experience with two handed sword weapons
Become a Veteran Knight
Gather enough experience with light weapons
Have 20 kills with Oil pot
Decapitate an opponent that is on fire.
Gather enough experience with dagger weapons
Kill 100 Men at Arms.
Gather enough experience with bastard weapons
Have 100 kills with the fists
Unlock all swords
Gather enough experience with one handed axe weapons
Gather enough experience with polearm weapons
Gather enough experience with bow weapons
Become a Veteran Vanguard
Become a Veteran Man at Arms
Decapitate 2 opponents with 1 swing
Gather enough experience with one handed blunt weapons
Gather enough experience with javelin weapons
Become a Veteran Archer
Gather enough experience with crossbows
Gather enough points to reach level 10
Gather enough experience with two handed axes weapons
Gather enough experience with two handed weapons
Gather enough experience with one handed sharp weapons
Gather enough points to reach level 5
Shoot 40 arrows into the heart
Get 10 Headshots with a ranged weapon in one game.