Here is the full list of all 50 Black Mesa achievements. It takes around 20-25 hours to unlock all of the achievements on Windows.
Find the snack supply canister.
Find each member of the missing research teams.
Send the Hidden Hat to Xen.
Deliver the finishing blow to Gonarch with your Crowbar.
Don't use the Cyanogen and let the Gonarch live.
Use Cyanogen to kill Gonarch.
Kill all Protozoans in the Borderworld.
Get whacked into oblivion in the ledge fight.
Escape the Hangar in Surface Tension without alerting the Soldiers.
Kill 10 Enemies with Tripmines.
Kill 10 enemies with a reprogrammed Sentry.
Assemble all the possible Scientists and Guards at the end of Office Complex.
Use the alternate path in Office Complex.
Interfere with the alarm and laptop in Anomalous Materials.
Accept G-Man’s offer of employment.
Decline G-Man’s offer of employment.
Defeat Nihilanth in under 4 minutes.
Take out all three Healing Crystals in Nihilanth’s Chamber at the same time.
Don't kill any Vortigaunts in the Borderworld.
Kill a Controller without killing any of its mind-controlled Vortigaunt slaves.
Use the welcome mat.
Skip the opening Xen island with a secret jump.
Wait too long to jump into the Lambda Teleporter.
Help the Barnacle and Headcrab find true love.
Drown in Lambda Core's coolant.
Use an entire clip of Gluon ammo in one continuous shot.
Kill 20 enemies with the Hivehand.
Kill an Icthyosaur with either the Tau or Gluon.
Overcharge it anyway.
Conduct all of the questionable research experiments.
Kill 5 enemies with one grenade.
Kill 10 enemies with Snarks.
Get killed by your own Snarks.
Kill a Headcrab using fire.
Kill a Barnacle with a Satchel.
Kill an Assassin with the .357 Magnum.
Headshot 20 enemies with the .357 magnum.
Kill 10 Airborne Headcrabs using the Shotgun.
Kill a Marine with their own grenade.
Perform surgical caffeine extraction from 20 machines.
Cook a Grenade for too long.
Get overtaken by a Headcrab's ample anterior.
Refuse to insert the specimen into the Anti-Mass Spectrometer.
Die in the AMS Beam before starting the experiment.
Pass the toilet paper to the scientist in need.
Ruin the microwave casserole.
Carry the Hidden Hat to Endgame.
Complete Interloper without taking any laser damage.
Escape the Gargantua’s Lair without taking any damage from Gargantuas.
View the *other* secret ending.