Here is the full list of all 64 Batman: Arkham City - there are Game of the Year Edition achievements.
Obtain 114 medals on the original Arkham City and Nightwing Bundle Pack campaigns (as Nightwing)
Obtain 78 medals on the original Arkham City and Nightwing Bundle Pack maps (as Nightwing)
Obtain 114 medals on the original Arkham City and Robin Bundle Pack campaigns (as Robin)
Obtain 78 medals on the original Arkham City and Robin Bundle Pack maps (as Robin)
Obtain all 108 medals on the original Arkham City campaigns (as Catwoman)
Obtain all 72 medals on the original Arkham City maps (as Catwoman)
Obtain all 108 medals on the original Arkham City campaigns (as Batman)
Complete every challenge in Arkham City - Main Story, Side Missions, Upgrades, Collectables, New Game Plus and Riddlers Revenge (as Batman)
Perform a perfect combo including all of Batman's combat moves (any play mode)
Destroy all Harley Balloons
Obtain 72 medals on the original Arkham City campaigns (as Batman)
Obtain 36 medals on the original Arkham City campaigns (as Batman)
Have 12 murderous dates with Calendar Man
Snap Flash an unarmed thug, an armed thug, an environmental object and a Titan
Use 5 different Quickfire gadgets in one fight as Robin in Harley Quinn's Revenge
Complete New Game Plus
Obtain all 72 medals on the original Arkham City maps (as Batman)
Obtain 48 medals on the original Arkham City maps (as Batman)
Obtain 24 medals on the original Arkham City maps (as Batman)
Complete all 40 of the Catwoman Riddler grid items
A moment of remembrance
Shield Bash 5 different thugs
Rescue all the hostages from Riddler
Defuse all bombs in 3 minutes or less
Zip Kick 5 different thugs
Complete one combat challenge without taking damage (any character)
Rescue the fifth hostage from Riddler
Rescue the fourth hostage from Riddler
Stop all assaults in Arkham City
Collect all of Batman's gadgets and upgrades
Use 5 different Quickfire gadgets in one fight (any play mode)
Track down the serial killer
Rescue the third hostage from Riddler
Retrieve your stolen goods
Reveal the mystery watcher
Complete all augmented reality training exercises
Stop the contract operative
The joke's on who?
Clean up the Dry Docks
Rescue the second hostage from Riddler
Find a way into the secret base
Stop the phone booth killer
Reunite the separated couple
Destroy it all
No crimefighter should be without this
Rescue the first hostage from Riddler
Time is running out
All the world is a stage
Don't look down
Steal the score of a lifetime
Fight for survival
Solve the first riddle
A deadly game of hide and seek
We are legion
Uncover the secret of Arkham City
Stop the unstoppable
Last man standing
Clear the airwaves
Drop in on an old friend
Hammer the point home
There is only one way in
Save the medical volunteers
Save the damsel, but is she in distress?
Become the Bat