Here is the full list of all 47 Batman: Arkham Asylum Game of the Year Edition achievements.
String up one henchman and drop him to surprise a second (any play mode)
Achieve 24 medals on predator
100% Complete
Achieve 16 medals on predator challenges
Catch a Batarang (any play mode)
Defeat Titan henchman without using Batarangs (any play mode)
Spirit of Amadeus Arkham revealed
Solve every riddle on the island
Perform a perfect combo including all of Batman's combat moves (any play mode)
Complete one predator challenge by using only Silent Takedowns and without being detected
Achieve 24 medals on combat challenges
Solve 85% of Riddler challenges
Achieve 16 medals on combat challenges
Deliver an explosive knock out blow to the Joker (Normal difficulty)
Deliver an explosive knock out blow to the Joker (Hard difficulty)
Deliver an explosive knock out blow to the Joker (Easy difficulty)
KO all the henchmen celebrating your arrival at the party
Defeat the giant Titan Ivy plant
Solve 70% of Riddler challenges
Achieve 8 medals on predator challenges
Ride a Titan henchman and knock down 5 thugs (any play mode)
Venture into Killer Croc's lair and come out alive
Conquer the effects of the Scarecrow's fear gas
Solve 55% of Riddler challenges
Defeat two Titan Henchmen at once
Solve 40% of Riddler challenges
Capture and lock up Harley Quinn
Achieve 8 medals on combat challenges
Save Dr. Young from being killed by Victor Zsasz
Face your biggest fears and keep your sanity
Complete one combat challenge without taking damage
Solve 25% of Riddler challenges
Gain access to Administration after it is locked down by the Joker
Glide continuously for over 100m
Defeat Bane
Survive the nightmare of the Scarecrow's fear gas
Complete a combo of 40 moves (any play mode)
Save all the doctors in medical
Solve 10% of Riddler challenges
Solve 5% of Riddler challenges
Escape from Intensive Treatment to the island surface
Survive the onslaught from the deformed Joker henchman
Rescue the guards and henchman from the Joker toxin in Decontamination
Complete a combo of 20 moves (any play mode)
Take down Zsasz in the Patient Pacification Chamber
Complete a combo of 10 moves (any play mode)
Complete a combo of 5 moves (any play mode)