Here is the full list of all 49 Agents of Mayhem achievements. It takes around 40-50 hours to unlock all of the achievements on Windows.
Complete "Operation: Machine Man."
Enter a secret room inside a LEGION lair.
Complete "Operation: Star Power."
Complete LEGION Alert Level by defeating the LEGION Captain.
Destroy a Ice Barrage Emplacement.
Build your first vehicle through blueprints.
Unlock 5 Warp Points through open world gameplay.
Destroy a Hate Machine Emplacement.
Get 15 "All Perfect" hacks.
Destroy a Dark Matter Fracking Station.
Run over Legion 10 times.
Complete a LEGION lair for the first time in Seoul.
Take over each type of emplacement location.
Jump agent vehicle 50 meters in one jump.
Swap out an agent's weapon with a new look.
Complete "Operation: Heaven Sent."
Deploy your first agent to any LEGION region.
Find and open a large loot chest.
Call in an agent vehicle for the first time.
Take over an Outpost from LEGION.
Destroy a Drop Pod Launcher Emplacement.
Use Gremlin Tech for the first time.
Equip an Upgrade Core to any agent.
Warp into the ARK for the first time.
Complete "Operation: Spinoff."
Equip your first gadget onto any agent.
Complete "Operation: Red Queen."
Complete "Operation: Madhouse."
Complete "Operation: Damocles."
Use mission replay to replay and complete 3 missions.
Destroy a Gravity Dominator.
Destroy a Golem in the open world.
Enter a secret room, inside a secret room, inside a LEGION lair.
Fully deck out Carnage a Trois in their signature outfits.
Fully deck out Franchise Force in their signature outfits.
Fully deck out the Bombshells in their signature outfits.
Fully deck out Firing Squad in their signature outfits.
Complete a 360 in the air while in a vehicle.
Complete 15 Connected Contracts.
Complete 30 MAYHEM & Agent Contracts.
Unlock and Complete all standard VR room training programs.
Hit 10 jumps in the city.
Collect all collectible Shards in game.
Fully upgrade all areas of the ARK.
Collect all agent vehicles.
Complete all Operations on Difficulty Level 7+.
Complete the Moscow Global Offensive.
Reach level 40 on any agent
Complete all agent personal missions and get all agents to level 20.